| 蒋政,张翼,李强,茆平,杨毅,焦岩.铜改性MIL-101吸附溶液中碘离子研究[J].装备环境工程,2017,14(1):66-70. JIANG Zheng,ZHANG Yi,LI Qiang,MAO Ping,YANG Yi,JIAO Yan.Iodide Ions in MIL-101 Adsorbent Solution Modified with Copper[J].Equipment Environmental Engineering,2017,14(1):66-70. |
| 铜改性MIL-101吸附溶液中碘离子研究 |
| Iodide Ions in MIL-101 Adsorbent Solution Modified with Copper |
| 投稿时间：2016-08-08 修订日期：2017-01-15 |
| DOI：10.7643/ issn.1672-9242.2017.01.016 |
| 中文关键词: 放射性碘 铜改性 MIL-101 掺杂量 吸附率 |
| 英文关键词:radioactive iodine copper doping modification MIL-101 doping amount adsorption rate |
| 基金项目:国家自然科学基金项目（21207066，11205089）；江苏省环境净化材料工程技术研究中心开放课题（KFK1504）；江苏高校优势学科建设工程资助项目。 |
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| Author | Institution |
| JIANG Zheng | School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
| ZHANG Yi | School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
| LI Qiang | School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
| MAO Ping | School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
| YANG Yi | 1.School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;2.Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM)，School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China |
| JIAO Yan | Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM)，School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China |
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| 中文摘要: |
| 目的 提升MIL-101对溶液中放射性碘离子的吸附性能。方法 开展铜掺杂改性MIL-101研究。利用SEM，XRD和比表面与孔径分析仪等表征方法对改性前后的材料进行物理性能分析，并考察不同Cu掺杂量、吸附时间和初始碘离子浓度对吸附效果的影响。结果 铜改性后吸附率明显增加，掺杂20％的铜时，材料的比表面积最大，吸附效果最佳；吸附速率随时间增大而降低，而吸附率随初始浓度减小而增大。结论 铜改性后的MIL-101对溶液中碘离子有更好的吸附效果，其吸附速率和吸附量都有明显的优势。 |
| 英文摘要: |
| Objective To improve the adsorption performance of MIL-101 on radioactive iodine ions in solution. Methods MIL-101 modified with copper doping was researched. Physical properties of materials before and after modification were analyzed with SEM, XRD, specific surface, pore size analyzer, etc. Moreover, effects of adsorption on the content of copper, adsorption time, initial concentration of iodide ions were studied. Results The adsorption rate of MIL-101 increased obviously after it is modified with copper. Especially when the content of copper is 20%, it had the best adsorption performance because maximum specific surface was achieved. The adsorption rate decreased with the increase of adsorption time, and increased with the decrease of initial concentration. Conclusion MIL-101 has better adsorption property and is dominant in both adsorption rate and adsorption capacity after it is modified with copper. |
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