张星,刘巍,李侠清,张全胜,冯雷雷,官庆卿,常峰.一种Cu-MOF缓蚀剂的复配研究[J].装备环境工程,2022,19(3):79-86. ZHANG Xing,LIU Wei,LI Xia-qing,ZHANG Quan-sheng,FENG Lei-lei,GUAN Qing-qing,CHANG Feng.Compounding of Cu-MOF Corrosion Inhibitor[J].Equipment Environmental Engineering,2022,19(3):79-86.
一种Cu-MOF缓蚀剂的复配研究
Compounding of Cu-MOF Corrosion Inhibitor
投稿时间:2021-12-15  修订日期:2022-01-07
DOI:10.7643/issn.1672-9242.2022.03.012
中文关键词:  Cu-MOF  复配  硫脲  六亚甲基四胺
英文关键词:Cu-MOF  compound  thiourea  hexamethylenetetramine
基金项目:
作者单位
张星 中石化胜利油田石油工程技术研究院,山东 东营 257000 
刘巍 中石化胜利油田石油工程技术研究院,山东 东营 257000 
李侠清 中石化胜利油田石油工程技术研究院,山东 东营 257000 
张全胜 中石化胜利油田石油工程技术研究院,山东 东营 257000 
冯雷雷 中石化胜利油田石油工程技术研究院,山东 东营 257000 
官庆卿 中石化胜利油田石油工程技术研究院,山东 东营 257000 
常峰 中石化胜利油田工程技术管理中心,山东 东营 257000 
AuthorInstitution
ZHANG Xing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
LIU Wei Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
LI Xia-qing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
ZHANG Quan-sheng Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
FENG Lei-lei Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
GUAN Qing-qing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, 257000, China 
CHANG Feng Engineering Technology Management Center of Sinopec Shengli Oilfield, Dongying, 257000, China 
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中文摘要:
      目的 对Cu-MOF进行复配,探究其最佳复配比例,以增强Cu-MOF的缓蚀效果。方法 通过静态失重挂片、电化学测试和表面形貌分析等手段,探究Cu-MOF与硫脲、六亚甲基四胺复配前后对Q235碳钢在1 mol/L HCl介质中缓蚀行为的变化。结果 单独使用50 mg/L的Cu-MOF时,碳钢的腐蚀速率为2.83 g/(m2.h)。使用硫脲、六亚甲基四胺与Cu-MOF进行复配后,碳钢在盐酸介质中的失重腐蚀速率均有了不同程度的下降,分别下降至1.28、1.14 g/(m2.h)。结论 硫脲和六亚甲基四胺与Cu-MOF复配,表现出很好的协同作用,碳钢表面形成的保护膜更加致密,缓蚀效率明显提升。
英文摘要:
      Thepurpose of this paper is to explored the optimal compounding ratio by compounding Cu-MOF,thereby obtain better corrosion inhibition effects of Cu-MOF. The corrosion inhibition behavior change of Cu-MOF before and after compounded with thiourea and hexamethylenetetramine on Q235 carbon steel in 1 mol/L HCl medium was investigated by the means of static weight-loss coupon test, electrochemical measurements and surface morphology analysis. When 50 mg/L Cu-MOF was used alone, the corrosion rate of carbon steel was 2.83 g/(m2.h). After using thiourea and hexamethylenetetramine with Cu-MOF for compounding, the weight-loss corrosion rate of carbon steel in hydrochloric acid solution has decreased with varying degrees, to 1.28 and 1.14 g/(m2.h) respectively. The compounding of thiourea and hexamethylenetetramine with Cu-MOF showed good synergistic effect. The protective film formed on the surface of carbon steel was denser and the corrosion inhibition efficiency was significantly improved.
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