李晗,魏小琴,邓家卫,滕俊鹏,赵阳,赵方超,刘世乡,周雪鹏,刘伟.电容式湿度传感器温-湿-盐雾耦合环境损伤效应与机理研究[J].装备环境工程,2023,20(7):161-167. LI Han,WEI Xiao-qin,DENG Jia-wei,TENG Jun-peng,ZHAO Yang,ZHAO Fang-chao,LIU Shi-xiang,ZHOU Xue-peng,LIU Wei.Environmental Damage Effect and Mechanism of Capacitive Humidity Sensor under the Coupling of Temperature-Humidity-Salt Spray[J].Equipment Environmental Engineering,2023,20(7):161-167.
电容式湿度传感器温-湿-盐雾耦合环境损伤效应与机理研究
Environmental Damage Effect and Mechanism of Capacitive Humidity Sensor under the Coupling of Temperature-Humidity-Salt Spray
投稿时间:2022-11-10  修订日期:2022-12-26
DOI:10.7643/issn.1672-9242.2023.07.020
中文关键词:  电容式湿度传感器  温-湿-盐雾  加速老化  环境损伤  损伤机理中图分类号:TJ01 文献标识码:A 文章编号:1672-9242(2023)07-0161-07
英文关键词:capacitive humidity sensor  temperature-humidity-salt spray  accelerated aging  environmental damage  damage mechanism
基金项目:
作者单位
李晗 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039;漠河大气环境材料腐蚀国家野外科学观测研究站,黑龙江 漠河 165301 
魏小琴 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039;漠河大气环境材料腐蚀国家野外科学观测研究站,黑龙江 漠河 165301 
邓家卫 陆军装备部驻重庆地区军事代表室,重庆 400042 
滕俊鹏 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039 
赵阳 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039;漠河大气环境材料腐蚀国家野外科学观测研究站,黑龙江 漠河 165301 
赵方超 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039 
刘世乡 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039 
周雪鹏 西南技术工程研究所,重庆 400039 
刘伟 西南技术工程研究所,重庆 400039;中国兵器装备集团 弹药贮存环境效应重点实验室,重庆 400039 
AuthorInstitution
LI Han Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China;Mohe Material Atmospheric Corrosion Station of National Outdoor Scientific Observation and Research, Heilongjiang Mohe 165301, China 
WEI Xiao-qin Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China;Mohe Material Atmospheric Corrosion Station of National Outdoor Scientific Observation and Research, Heilongjiang Mohe 165301, China 
DENG Jia-wei Military Representative Office of Army Equipment Department in Chongqing, Chongqing 400042, China 
TENG Jun-peng Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China 
ZHAO Yang Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China;Mohe Material Atmospheric Corrosion Station of National Outdoor Scientific Observation and Research, Heilongjiang Mohe 165301, China 
ZHAO Fang-chao Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China 
LIU Shi-xiang Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China 
ZHOU Xue-peng Southwest Institute of Technology and Engineering, Chongqing 400039, China 
LIU Wei Southwest Institute of Technology and Engineering, Chongqing 400039, China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing 400039, China 
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中文摘要:
      目的 研究电容式湿度传感器在温-湿-盐雾耦合环境作用下的性能退化规律和失效机理。方法 将电容式湿度传感器放置在三因素循环(85 ℃+85%RH→40 ℃+0.05%NaCl中性盐雾→35 ℃+50%RH干燥)环境下进行加速老化试验,定期取样,分析响应时间和测量精度退化规律,研究温-湿-盐雾对电容式湿度传感器的环境损伤机制。结果 在三因素环境下老化7 d,湿度传感器在标准湿度(>50%RH)环境下感应异常;老化14 d,湿度传感器在每种标准湿度环境下感应异常。测试发现,湿敏电容的电容量偏大,绝缘电阻偏小,损耗角正切偏大,确定湿敏电容失效。湿度传感器在温-湿-盐雾环境下,在盐雾阶段,盐粒子沉积在湿敏材料表面,在干燥阶段水分挥发,最终在湿敏材料表面形成不规整颗粒物,造成湿敏电容绝缘性能降低。在通电测试时,不规整颗粒物在电场作用下易发生尖端发电,使得感湿材料绝缘性能下降,同时伴随有腐蚀和击穿烧蚀,使湿敏电容发生失效。结论 湿度传感器在温-湿-盐雾环境下,盐粒子易附着在感湿材料上,在通电环境下发生击穿烧蚀,造成湿度传感器功能失效。
英文摘要:
      The work aims to study the degradation law and failure mechanism of capacitive humidity sensor under the coupling environment of temperature-humidity-salt spray. The capacitive humidity sensor was placed in the three-factor (85 ℃ + 85%RH → 40 ℃ + 0.05%NaCl neutral salt spray → 35 ℃ + 50%RH drying) cycle environment for accelerated aging test and sampled regularly to analyze the degradation law of response time and measurement accuracy and study the environmental damage mechanism of temperature-humidity-salt spray on capacitive humidity sensor. After aging for 7 days in the three-factor environment, the humidity sensor in the standard humidity (> 50%RH) environment had abnormal induction. After aging for 14 days, the humidity sensor in every standard humidity environment had abnormal induction. When the humidity sensitive capacitor was tested, it was found that the capacitance was rather large, the insulation resistance was rather small, and the loss angle tangent was rather large, which determined the failure of the humidity sensitive capacitor. In temperature-humidity-salt spray environment, particles deposited on the surface of humidity sensitive material in salt spray phase. In drying stage, moisture volatilized and irregular particles formed on the surface of humidity sensitive material, which reduced the insulation performance of humidity sensitive capacitor. In the current test, irregular particles were prone to generating power at the tip under the action of electric field, which degraded the insulation performance of humidity sensitive material, accompanied by corrosion, breakdown and ablation, and eventually the failure of humidity sensitive capacitor. When humidity sensor is in temperature-humidity-salt spray environment, salt particles are easy to adhere to the humidity sensitive material and breakdown and ablation occur in the current environment, resulting in the function failure of humidity sensor.
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