Research Progress on Mechanism of Fenton Reaction and Its Involved Photocatalytic System
Received:May 06, 2019  Revised:August 19, 2019
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DOI:10.7643/issn.1672-9242.2019.09.014
KeyWord:photocatalysis  Fenton reaction  mechanism  electron-hole pair  hydroxyl radical (OH)
     
AuthorInstitution
GAO Ying Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao , China;University of Chinese Academy of Sciences, Beijing , China;Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology Qingdao, Qingdao , China
DUAN Ji-zhou Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao , China;Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology Qingdao, Qingdao , China
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Abstract:
      This paper reviewed the mechanism of photocatalytic degradation of organic pollutants and sterilization, among them the main content of organic matter degradation mechanism were holes and hydroxyl radical (OH) oxidative decomposition of organic pollutants, the sterilization mechanism and degradation of organic matter, namely electrons and holes or oxygen free radicals attack bacteria cell wall, cell membrane and intracellular constituents, the bacterial inactivation. The mechanism of Fenton reaction was summarized from Fe2+ and Cu2+ ion-mediated Fenton reactions respectively, and the conclusion that the two ion-mediated Fenton reactions had similar mechanisms was drawn. Finally, the current research status and mechanism of introducing Fenton reaction into photocatalytic system were described, and it was found that introducing Fenton reaction into photocatalytic system was an effective way to promote photocatalytic activity.
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