Effect of Marine Atmospheric Environment on the Properties of Envelope Protective Materials
Received:February 16, 2023  Revised:April 18, 2023
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DOI:10.7643/issn.1672-9242.2023.10.016
KeyWord:marine atmospheric environment  envelope protective materials  storage test  water vapor transmission  shelter storage  warehouse storage  multi-level moisture transmission  long-term storage performance
                 
AuthorInstitution
XU Hao Southwest Institute of Technique and Engineering, Chongqing , China
YANG Sen Southwest Institute of Technique and Engineering, Chongqing , China
YANG Huan Southwest Institute of Technique and Engineering, Chongqing , China
XING Dong-hui Southwest Institute of Technique and Engineering, Chongqing , China
ZHOU Song-shan Southwest Institute of Technique and Engineering, Chongqing , China
DAI Wen-jun Southwest Institute of Technique and Engineering, Chongqing , China
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Abstract:
      The work aims to explore the performance degradation law of aluminum-plastic envelope protective materials under long-term storage in hygrothermal marine atmospheric environment. By optimizing the layer structure, new envelope protective materials were prepared with SiOx evaporated biaxially stretched polyester film as the outer reinforcement layer and PA6 coextruded EVOH biaxially stretched film as the inner reinforcement layer. Then, storage tests were carried out in the warehouse and shelter of Marine Atmosphere Environmental Test Station. By testing critical properties such as water vapor transmission, oxygen transmission, peeling force, breaking force and surface resistivity, the time-performance effect curve was established. Meanwhile, the internal humidity curve of materials and corrosion state of carbon steel disc were recorded, so as to evaluate the effect trend of marine atmospheric environment on the performance of envelope protective materials. After 180 days of storage, the water vapor transmission was still less than 0.3 g/(cm2.24 h), the moisture resistance of the self-developed new envelope protective materials in the shelter storage and warehouse storage environment were improved by 29.8% and 31.5% respectively, and peeling force and breaking force did not decrease significantly and surface resistivity was at a range of 109~1011 Ω. By reducing the interaction between moisture molecules and outer enhancement layer molecules, the barrier ability of the envelope protective material can be effectively improved, which verifies the scientific nature of the multi-level moisture transmission concept.
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