张庆吉,荆江平,孙萌萌,陈卓元,李焰.碳量子点掺杂氮化碳提高的光电化学阴极保护性能研究[J].装备环境工程,2018,15(10):21-26. ZHANG Qing-ji,JING Jiang-ping,SUN Meng-meng,CHEN Zhuo-yuan,LI Yan.Enhancement of Photoelectrochemical Performance of Carbon Quantum Dots Doped Carbon Nitride[J].Equipment Environmental Engineering,2018,15(10):21-26. |
碳量子点掺杂氮化碳提高的光电化学阴极保护性能研究 |
Enhancement of Photoelectrochemical Performance of Carbon Quantum Dots Doped Carbon Nitride |
投稿时间:2018-07-16 修订日期:2018-10-25 |
DOI:10.7643/ issn.1672-9242.2018.10.004 |
中文关键词: 碳量子点 g-C3N4 光电化学阴极保护技术 腐蚀防护 |
英文关键词:carbon quantum dots g-C3N4/C-Dots-M photoelectrochemical cathodic protection technology corrosion protec-tion |
基金项目:国家自然科学基金(41676069,41576114);青岛市创新领军人才项目(15-10-3-15-(39)-zch) |
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Author | Institution |
ZHANG Qing-ji | 1. China University of Petroleum, Qingdao 266580, China;2. Key Laboratory of Marine Corrosion and Bio-fouling, IOCAS, Qingdao 266000, China |
JING Jiang-ping | 2. Key Laboratory of Marine Corrosion and Bio-fouling, IOCAS, Qingdao 266000, China |
SUN Meng-meng | 2. Key Laboratory of Marine Corrosion and Bio-fouling, IOCAS, Qingdao 266000, China |
CHEN Zhuo-yuan | 2. Key Laboratory of Marine Corrosion and Bio-fouling, IOCAS, Qingdao 266000, China |
LI Yan | 1. China University of Petroleum, Qingdao 266580, China |
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中文摘要: |
目的 研究g-C3N4/C-Dots-M复合材料的光电化学阴极保护性能。方法 采用X射线衍射(XRD)、扫描电子显微镜(SEM)和紫外可见漫反射光谱技术对样品的晶体结构、微观形貌和光吸收性能进行表征。通过电化学测试可见光照射下g-C3N4/C-Dots-M复合材料光电极偶联316L不锈钢后的光电化学阴极保护电流密度和电位变化曲线,研究材料的光电化学阴极保护性能。结果 可见光照射下,该偶联体系的光致混合电位下降至?0.43 V(vs. Ag/AgCl),光电化学阴极保护电流密度达到4.3 μA/cm。结论 得益于碳量子点优异的电子传导特性,g-C3N4/C-Dots-550复合材料的光电化学阴极保护性能比纯g-C3N4的明显增强。该复合材料在光电化学阴极保护方面展现了较大的应用潜力。 |
英文摘要: |
Objective To research the photoelectrochemical cathodic protection performance of g-C3N4/C-Dots-M of the composite material. Methods The structure and morphology of the samples were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and UV-Vis diffuse reflectance spectroscopy. The photoelectrochemical cathodic protection performance was studied by testing the cathodic protection current density-time and potential-time of g-C3N4/C-Dots- Mcomposite material under visible light illumination. Results Under visible light illumination, the mixed potential of the g-C3N4/C-Dots-550 composite coupled with 316L SS dropped to ?0.43 V, and the photoinduced current density of the couple reached 4.3 μA/cm2. Conclusion Compared to pure g-C3N4, g-C3N4/C-Dots-M composites showed enhanced photoelectrochemical cathodic protection performance. This is due to the excellent electrical conductivity of carbon quantum dots. This composite shows tremendous potential in application of photoelectrochemical cathodic protection. |
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