The radiation evironmental effects of Ra226, Th232 Radionuclides in the sludge from battery and electroplating factories
Received:September 20, 2016  Revised:November 23, 2016
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DOI:10.7643/ issn.1672-9242.2016.06.013
KeyWord:Battery sludge  Eletroplating sludge  Radionuclides  Gamma Energy Spectrum Analysis  Enrichment Factor
                       
AuthorInstitution
陈冬
颜学武
廖雅杰
张宗祥
吴晶
毛慧
刘颖
杨毅
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Abstract:
      The radionuclides, such as 228Ac, 212Pb, 212Bi, 208Tl, 214Pb, 214Bi and 40K, occurring in the sludge samples from five lead-acid battery or electroplating factories in JiangSu province were analyzed on High Purity Germanium crystal spectrometer(HPGe). The radioactivity of each radionuclides were calculated with data obtained on HPGe. The estimated annual average effective dose contributed by these sludge samples was 44.8(19.2~50.3)μSv.a-1 with Monte Carlo N Particle Transport Code(MCNP) dose rate conversion factor. The Enrich Factor(EF) of 232Th was about (0.478~2.217), and EF of 226Ra about (2.509~4.115), indicting that the radionuclides were enriched during the manufacture process to some extent. In addition, There were observed significant positive correlations between the amount of heavy metal chromium and lead and radionuclides 232Th and radioactivity in chromium sludge samples with the Pearson correlation matrix range (0.411~0.576),(0.494~0.797) and (0.455~0.844),(0.371~0.821), respectively. The Pearson correlation matrix for chromium and radium equivalent activity(Raeq) reach to 0.884 in SDCS, Moreover,lead and Raeq reach to 0.820,0.801 in YXCS,MXCS, respectively, indicating the use of relative heavy metals concentrations to predict radioactivity for studied sludge is possible.
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