Corrosion Behavior of Nano-coating/Aluminum Alloy in Seawater Solution with Different pH Values
Received:July 29, 2019  Revised:August 19, 2019
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DOI:10.7643/issn.1672-9242.2020.01.021
KeyWord:nano coating  pH  water solution  EIS spectra
                    
AuthorInstitution
MU Xian-lian Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
XIE Peng-fei Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
JIN Tao Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
ZHANG Deng Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
ZHAO Lian-hong Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
WANG Hao-wei Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
LIAO Sheng-zhi Aviation Key Laboratory of Science and Technology on Structure Corrosion Prevention and Control, China Special Vehicle Research Institute, Jingmen , China
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Abstract:
      The paper aims to evaluate the corrosion behavior of nano-coating/aluminum alloy in seawater solution with different pH values. Through testing the EIS value of nano coating/aluminum alloy in sea solution of different pH values, the evolution law of impedance spectra and Bode spectrogram of samples were analyzed to establish different electrode impedance models of different EIS spectra, and the ZView software was used to analyze electrochemical impedance spectroscopy of the coating system in different periods, to obtain the change tendency of the coating resistance and the corrosion failure rate of the nano coating system in sea solution of different pH values. With the increase of immersion time and the decrease of pH value, the corrosion damage failure rate of nano-coating/aluminum alloy system generally increased in the early immersion period; but in the middle and later stages, as corrosion products gradually blocked the coating pores, the penetration rate of corrosion medium to the surface of aluminum alloy gradually decreased. For the nano-coating systems with different pH values, the corrosion failure rate is as follows:coating 1 immersed in seawater of pH 2.0 failed the fastest, followed by coating 2 immersed in seawater of pH 4.0, and finally followed by coating 1 immersed in seawater of pH 6.0. The coating systems should be fitted with equivalent circuit model C.
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