Preparation of Dual-valent Polysilicate Aluminum Ferric Sulfate by Pressure Acid Leaching and Its Removal of Cyanobacteria
Received:January 23, 2020  Revised:February 26, 2020
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DOI:10.7643/issn.1672-9242.2020.07.008
KeyWord:solidresidue of K-feldspar  microcystis aeruginosa  pressure acid leaching  coupling coagulation
                    
AuthorInstitution
LIANG Yu-jia Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
Eng da Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
LYU Ying Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
HAN Bo-lei Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
XIE Hui-fang Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
QU Hong-xia School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing , China
CHEN Shou-wen Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing , China
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Abstract:
      The paper aims to develop a multifunctional dual-valent flocculant from the solid residues of K-feldspar, study its characteristics in removal of microcystis aeruginosa, to achieve comprehensive utilization of K-feldspar and provide a new flocculant for water treatment. The pressure acid leaching (PAL) process was used to extract aluminum and iron from solid residues and the dual-valent PSAFS was prepared by introducing Fe (II). Microcystis aeruginosa, the model of cyanobacteria, was used to determine the algal removal characteristics and coupling effects with H2O2. Nearly 100% aluminum and 85.6% iron were extracted at H2SO4 concentration 2.8 mol/kg, solid-liquid ratio 1:3, temperature 105 ℃ and PAL time 2 h. The dual-valent PSAFS showed excellent ability to remove microcystis aeruginosa and the introduction of Fe (II) can broaden the pH range of flocculant application. This new coagulant could deactivate more microcystis cell when H2O2 was present. The dual-valent PSAFS can be prepared from solid residues of K-feldspar after potassium extractions by PAL process in a green and economical way. It is a promising multifunctional flocculant.
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