Corrosion Behavior of B10 Copper-nickel Alloy after Full Immersion in Indoor Simulated Seawater and Real Seawater
Received:March 20, 2020  Revised:April 25, 2020
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DOI:10.7643/issn.1672-9242.2020.08.010
KeyWord:B10 copper-nickel alloy  full immersion  seawater  corrosion
                 
AuthorInstitution
PENG Wen-shan State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
DUAN Ti-gang State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
HOU Jian State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
MA Li State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
LIU Shao-tong State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
GUO Wei-min State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute LSMRI, Qingdao , China
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Abstract:
      The work aims to study the corrosion regularity of B10 copper-nickel alloy in the seawater immersion zone of Qingdao harbor. The full immersion experiment was carried out respectively in indoor simulated seawater and real seawater of harbor. The corrosion morphology, corrosion rate and pitting depth of B10 copper-nickel alloy after full immersion in seawater were compared and analyzed by 3D video photography, electrochemical test and weightless analysis. In the indoor simulated environment, there was an increasing trend for the pitting depth of B10 copper-nickel alloy as the immersion period increased. The corrosion rate and pitting depth of B10 copper-nickel alloy after immersion for 180 days in the real sea environment were smaller than those in the indoor simulated environment. In the indoor simulated environment, the main corrosion products of B10 copper-nickel alloy were Cu2O, Cu2(OH)3Cl and Cu(OH)2. Higher levels of Cu2O inhibited the marine fouling. Due to different seawater environments, there are significant differences in corrosion morphology, corrosion rate and pitting depth of B10 copper-nickel alloy in indoor simulation test and real sea test.
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