Crevice Corrosion of 316L Stainless Steel in Coastal Waters of South China Sea
Received:September 04, 2020  Revised:September 29, 2020
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DOI:10.7643/issn.1672-9242.2021.01.015
KeyWord:316L stainless steel  in situ marine exposure  crevice corrosion  corrosion behavior  microorganism, pitting
                    
AuthorInstitution
LI Hui-xin CNOOC Research Institute Co., Ltd., Beijing , China
LI Da-peng CNOOC Research Institute Co., Ltd., Beijing , China
WANG Mao-mao Safetech Research Institute, Beijing , China
CHANG Wei CNOOC Research Institute Co., Ltd., Beijing , China
ZHANG Lei Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing , China
SONG Ji-wen CNOOC Information Technology Co., Ltd., Beijing , China
WANG Xiu-yun Safetech Research Institute, Beijing , China
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Abstract:
      The aim of this study is to investigate the crevice corrosion of 316L stainless steel in coastal water of South China Sea. Crevice corrosion and pitting corrosion samples were immersed in coastal waters at the depth of about 170m in South China Sea. Optical microscope, scanning electron microscopy, energy-dispersive spectrometry and fluorescence test were carried out to characterize the corrosion products of 316L stainless steel. The results showed that 316L stainless steel is susceptible to crevice corrosion in marine environment. After the initial 120h of immersion, corrosion products and localized damage were observed on the crevice sample surface, while scratch marks were still clearly visible on the pitting sample surface. As the dissolved oxygen inside crevice depleted at the initial stage and the oxygen outside was difficult to diffuse inward, an oxygen concentration cell formed between the parts of steel insides and outside crevice, then the crevice corrosion was promoted. Because of the catalysis of Cl‒ ions and metabolism of microorganism, steel inside crevice suffered from pitting corrosion. Corrosion products accumulated and a groove formed at crevice mouth after a longer period of immersion.
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