Thermal Decomposition of Extinguished AP/HTPB Base Bleed Propellant under Condition of Transient Depressurization
Received:December 13, 2021  Revised:March 14, 2022
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DOI:10.7643/issn.1672-9242.2022.03.007
KeyWord:thermal decomposition  DSC  extinguished under condition of transient depressurization  AP/HTPB base bleed propellant  kinetic parameters
              
AuthorInstitution
SHEN Hui Haiying Enterprise Group Co., Ltd., Wuxi , China
XU Chong Haiying Enterprise Group Co., Ltd., Wuxi , China
ZHANG Pei-xin Haiying Enterprise Group Co., Ltd., Wuxi , China
LIU Yong-qiang Haiying Enterprise Group Co., Ltd., Wuxi , China
XU Peng Haiying Enterprise Group Co., Ltd., Wuxi , China
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Abstract:
      In order to analyze the characteristics of extinguished AP/HTPB base bleed propellant under condition of transient depressurization, the extinguished AP/HTPB base bleed propellant samples were prepared by semi-closed bomb. Thermal decomposition experiments of the micro samples were carried out by using DSC at three heating rates, the experimental results were comparatively analyzed with the original samples. The results show that at the same heating rate, the shape of exothermic peak in the DSC curve of the extinguished AP/HTPB base bleed propellant under condition of transient depressurization changed from the "M-type" to "inverted V-shaped", and the peak temperatures is lower than the exothermic peak temperature of the original sample. The activation energy of endothermic peak is 7.2%~62.5% higher than that of the original sample, but the activation energy of the exothermic peak is 14%~21% lower than that of the original sample.
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