Compounding of Cu-MOF Corrosion Inhibitor
Received:December 15, 2021  Revised:January 07, 2022
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DOI:10.7643/issn.1672-9242.2022.03.012
KeyWord:Cu-MOF  compound  thiourea  hexamethylenetetramine
                    
AuthorInstitution
ZHANG Xing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
LIU Wei Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
LI Xia-qing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
ZHANG Quan-sheng Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
FENG Lei-lei Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
GUAN Qing-qing Petroleum Engineering Technology Institute of Sinopec Shengli Oilfield, Dongying, , China
CHANG Feng Engineering Technology Management Center of Sinopec Shengli Oilfield, Dongying, , China
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Abstract:
      Thepurpose of this paper is to explored the optimal compounding ratio by compounding Cu-MOF,thereby obtain better corrosion inhibition effects of Cu-MOF. The corrosion inhibition behavior change of Cu-MOF before and after compounded with thiourea and hexamethylenetetramine on Q235 carbon steel in 1 mol/L HCl medium was investigated by the means of static weight-loss coupon test, electrochemical measurements and surface morphology analysis. When 50 mg/L Cu-MOF was used alone, the corrosion rate of carbon steel was 2.83 g/(m2.h). After using thiourea and hexamethylenetetramine with Cu-MOF for compounding, the weight-loss corrosion rate of carbon steel in hydrochloric acid solution has decreased with varying degrees, to 1.28 and 1.14 g/(m2.h) respectively. The compounding of thiourea and hexamethylenetetramine with Cu-MOF showed good synergistic effect. The protective film formed on the surface of carbon steel was denser and the corrosion inhibition efficiency was significantly improved.
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